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Organic Chemistry: Distillation Basics

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Organic Chemistry: Distillation Basics

A refinery receives crude oil, a mixture of many hydrocarbons. Your task is to work out how fractional distillation separates the mixture and why the fractions are useful.

How the column works

Crude oil is heated so that most of it vaporises. The vapour enters a fractionating column, which is hottest near the bottom and cooler near the top. As vapours rise, they cool and condense at different heights. A fraction is a group of hydrocarbons with similar boiling points. Shorter-chain hydrocarbons usually have lower boiling points and are collected higher in the column. Longer-chain hydrocarbons usually have higher boiling points and condense lower down. Refinery gases are collected at the top of the column, petrol in the upper section, diesel in the lower section, and bitumen residue remains at the bottom. Petrol is used as fuel for many cars, and bitumen is used for road surfacing or roofing. The fractions are mixtures, not single pure substances.

1.What is crude oil: a pure substance or a mixture? Use the passage to explain your choice.
2.Which property is mainly used to separate the hydrocarbons in fractional distillation?
  • Their boiling points
  • Their colours
  • Their magnetic properties
  • Their electrical conductivity
3.According to the passage, which fraction is collected highest, and which remains lowest in the column?
4.Select the best explanation for why a shorter-chain hydrocarbon tends to condense higher in the column.
  • It has a lower boiling point, so it condenses in a cooler part of the column.
  • It has a higher boiling point, so it condenses in a cooler part of the column.
  • It is heavier in colour, so it floats to the top.
  • It cannot vaporise when crude oil is heated.
5.Match each fraction with its general position in the column.
  • Petrol
  • Diesel
  • Bitumen residue
  • Bottom
  • Upper section
  • Lower section
6.True or false? Each fraction collected from crude oil is a single pure hydrocarbon.
TrueFalse
7.A refinery technician finds a fraction with a higher boiling point than petrol. Would you expect it to condense above or below the petrol outlet? Explain using the column’s temperature gradient.
8.In your own words, explain how heating and cooling help separate crude oil into fractions.
9.Name one everyday use for petrol and one use for bitumen, using the passage.

2 printable pages

  • Organic Chemistry: Distillation Basics, page 1 of 2: How the column works

    Page 1

  • Organic Chemistry: Distillation Basics, page 2 of 2: 4. Select the best explanation for why a shorter-chain hydrocarbon tends to condense…

    Page 2

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